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Pd-Catalyzed cyclization reactions of acetylene-containing α-amino acids

✍ Scribed by Larissa B. Wolf; Kim C.M.F. Tjen; Floris P.J.T. Rutjes; Henk Hiemstra; Hans E. Schoemaker

Book ID: 104259436
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 335 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)00910-1

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✦ Synopsis

Acetylene-containing amino acids, obtained in enantiopure form via an enzymatic resolution process, serve as versatile intermediates in the synthesis of various highly functionalized heterocycles. The key transformations, intramolecular OC-and NC-bond formation, proceed via Pd-catalysis.

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