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Pd-Catalyzed Allylic Alkylation of Secondary Nitroalkanes.

✍ Scribed by Keisuke Maki; Motomu Kanai; Masakatsu Shibasaki


Publisher
John Wiley and Sons
Year
2007
Weight
44 KB
Volume
38
Category
Article
ISSN
0931-7597

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Application of SDP Ligands for Pd-Cataly
✍ Jian-Hua Xie; Hai-Feng Duan; Bao-Min Fan; Xu Cheng; Li-Xin Wang; Qi-Lin Zhou 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 2 views

## Abstract Chiral spiro diphosphines (SDP) are efficient ligands for the Pd‐catalyzed asymmetric allylic alkylation of 1,3‐diphenyl‐2‐propenyl acetate with dimethyl malonate and related nucleophiles. The newly synthesized ligand DMM‐SDP (**1e**) with 3,5‐dimethyl‐4‐methoxy groups on the __P__‐phen