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Ferrocenylphosphine—Imine Ligands for Pd-Catalyzed Asymmetric Allylic Alkylation.

✍ Scribed by Xiangping Hu; Huicong Dai; Xinquan Hu; Huilin Chen; Junwei Wang; Changmin Bai; Zuo Zheng

Publisher: John Wiley and Sons
Year: 2003
Weight: 131 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200303034

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## Abstract Chiral spiro diphosphines (SDP) are efficient ligands for the Pd‐catalyzed asymmetric allylic alkylation of 1,3‐diphenyl‐2‐propenyl acetate with dimethyl malonate and related nucleophiles. The newly synthesized ligand DMM‐SDP (**1e**) with 3,5‐dimethyl‐4‐methoxy groups on the __P__‐phen