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Versatile Ligands for Palladium-Catalyzed Asymmetric Allylic Alkylation

✍ Scribed by Peter Dierkes; Shailesh Ramdeehul; Laurent Barloy; Andre De Cian; Jean Fischer; Paul C. J. Kamer; Piet W. N. M van Leeuwen; John A. Osborn

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
114 KB
Volume
37
Category
Article
ISSN
0044-8249

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Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of Ketone Enolates
✍ Barry M. Trost; Gretchen M. Schroeder πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 390 KB πŸ‘ 1 views

## Abstract Palladium‐catalyzed asymmetric allylic alkylation of nonstabilized ketone enolates to generate quaternary centers has been achieved in excellent yield and enantioselectivity. Optimized conditions consist of performing the reaction in the presence of two equivalents of LDA as base, one e