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Highly Enantioselective Pd-Catalyzed Allylic Alkylations of Acyclic Ketones

✍ Scribed by Xiao-Xia Yan; Chun-Gen Liang; Yan Zhang; Wei Hong; Bo-Xun Cao; Li-Xin Dai; Xue-Long Hou

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
94 KB
Volume
44
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

Palladium-Catalyzed Diastereoselective a
Palladium-Catalyzed Diastereoselective and Enantioselective Allylic Alkylations of Ketone Enolates
✍ Manfred Braun; Thorsten Meier; Frank Laicher; Panos Meletis; Mesut Fidan πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 297 KB πŸ‘ 1 views

## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladium‐catalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenyl‐ and dimethyl‐substituted allylic substrates **1a** and **1b** are reacted with cyclohexanone