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Pd 0 -Catalyzed Hydrogenolysis of a Bicyclic Allylic Diacetate

✍ Scribed by Muchow, Gunter; Brunel, Jean Michel


Book ID
121227510
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
491 KB
Volume
2013
Category
Article
ISSN
1434-193X

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πŸ“œ SIMILAR VOLUMES


Evidence of Formation of an exo-Ο€-Allyl
✍ JeanΒ Michel Brunel; Michel Maffei; GΓΌnter Muchow; GΓ©rard Buono πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 295 KB πŸ‘ 1 views

The palladium(0)-catalyzed alkylation of 2,3-bis(acetoxymethyl)bicyclo[2.2.1]hepta-2,5-diene 1 with malonate-type enolates as nucleophiles is investigated. A monoalkylated product is formed first, and undergoes (depending on the nucleophile used) a second intramolecular reaction leading to [a]

Experimental Evidence on the Existence o
✍ JeanΒ Michel Brunel; Michel Maffei; GΓΌnter Muchow; GΓ©rard Buono πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 292 KB πŸ‘ 1 views

The Pd 0 -catalyzed alkylation of 1 by sodiodimethylmalonate led to the formation of two tricyclic diastereomers 2a and 2b. The structure of the major endo diastereomer 2b has been Scheme 1. Pd 0 -catalyzed alkylation of allylic bicyclic diacetate 1 [a] E.