Evidence of Formation of an exo-π-Allyl
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Jean Michel Brunel; Michel Maffei; Günter Muchow; Gérard Buono
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Article
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2000
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John Wiley and Sons
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English
⚖ 295 KB
The palladium(0)-catalyzed alkylation of 2,3-bis(acetoxymethyl)bicyclo[2.2.1]hepta-2,5-diene 1 with malonate-type enolates as nucleophiles is investigated. A monoalkylated product is formed first, and undergoes (depending on the nucleophile used) a second intramolecular reaction leading to [a]