𝔖 Bobbio Scriptorium
✦   LIBER   ✦

P(CH 3 NCH 2 CH 2 ) 3 N: A Nonionic Superbase for Efficient Dehydrohalogenation

✍ Scribed by Arumugam, Subramaniam; Verkade, John G.

Book ID
120828692
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
174 KB
Volume
62
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

P(MeNCH2CH2)3N: An efficient nonionic su
P(MeNCH2CH2)3N: An efficient nonionic superbase for Wittig and Wittig-Horner reactions
✍ Zhigang Wang; John G. Verkade πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 133 KB πŸ‘ 1 views

The strong non-ionic base P(MeNCH 2 -CH 2 ) 3 N 1 is an efficient base for conversion of [RCH 2 PPh 3 ]X and RCH 2 P(O)(OEt) 2 to their corresponding ylides under mild conditions. Reaction of the ylides (generated in situ) with benzaldehyde give the corresponding alkenes in high yield.

ChemInform Abstract: P(MeNCH2CH2)3N: An
ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Nonionic Superbase for Wittig and Wittigβ€”Horner Reactions.
✍ Zhigang Wang; John G. Verkade πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

P(MeNCH 2 CH 2 ) 3 N: An Efficient Nonionic Superbase for Wittig and Wittig-Horner Reactions. -The strong non-ionic title base effectively deprotonates triphenylphosphonium salts (I) and phosphonates (IV) under mild conditions. Reaction of the ylides generated with aldehydes provides an efficient a