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ChemInform Abstract: P(CH3NCH2CH2)3N: A Nonionic Superbase for Efficient Dehydrohalogenation.

✍ Scribed by S. ARUMUGAM; J. G. VERKADE

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: P(MeNCH2CH2)3N: An
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P(MeNCH 2 CH 2 ) 3 N: An Efficient Nonionic Superbase for Wittig and Wittig-Horner Reactions. -The strong non-ionic title base effectively deprotonates triphenylphosphonium salts (I) and phosphonates (IV) under mild conditions. Reaction of the ylides generated with aldehydes provides an efficient a

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The strong non-ionic base P(MeNCH 2 -CH 2 ) 3 N 1 is an efficient base for conversion of [RCH 2 PPh 3 ]X and RCH 2 P(O)(OEt) 2 to their corresponding ylides under mild conditions. Reaction of the ylides (generated in situ) with benzaldehyde give the corresponding alkenes in high yield.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v