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ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Desulfurizing Reagent.

✍ Scribed by Zhengkun Yu; John G. Verkade

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

πŸ“œ SIMILAR VOLUMES

P(MeNCH2CH2)3N: An efficient desulfurizi
P(MeNCH2CH2)3N: An efficient desulfurizing reagent
✍ Zhengkun Yu; John G. Verkade πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 137 KB πŸ‘ 1 views

The nonionic superbase P(MeNCH 2 CH 2 ) 3 N (A) efficiently desulfurizes trisulfides to disulfides and monosulfides, disulfides to monosulfides, and propylene sulfide to propene. S‫ב‬P(MeNCH 2 CH 2 ) 3 N (B) was formed as the sulfur acceptor. P(NMe 2 ) 3 was a much poorer desulfurizing agent than A

ChemInform Abstract: P(MeNCH2CH2)3N: An
ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Nonionic Superbase for Wittig and Wittigβ€”Horner Reactions.
✍ Zhigang Wang; John G. Verkade πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

P(MeNCH 2 CH 2 ) 3 N: An Efficient Nonionic Superbase for Wittig and Wittig-Horner Reactions. -The strong non-ionic title base effectively deprotonates triphenylphosphonium salts (I) and phosphonates (IV) under mild conditions. Reaction of the ylides generated with aldehydes provides an efficient a

ChemInform Abstract: P(MeNCH2CH2)3N: An
ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Catalyst for the Synthesis of Substituted Ethyl Benzofuran-2-carboxylates.
✍ Bosco A. D'Sa; Philip Kisanga; John G. Verkade πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

P(MeNCH2CH2)3N: An efficient nonionic su
P(MeNCH2CH2)3N: An efficient nonionic superbase for Wittig and Wittig-Horner reactions
✍ Zhigang Wang; John G. Verkade πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 133 KB

The strong non-ionic base P(MeNCH 2 -CH 2 ) 3 N 1 is an efficient base for conversion of [RCH 2 PPh 3 ]X and RCH 2 P(O)(OEt) 2 to their corresponding ylides under mild conditions. Reaction of the ylides (generated in situ) with benzaldehyde give the corresponding alkenes in high yield.