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Palladium/BINAP(S)-Catalyzed Asymmetric Allylic Amination

โœ Scribed by Faller, J. W.; Wilt, Jeremy C.


Book ID
120065912
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
161 KB
Volume
7
Category
Article
ISSN
1523-7060

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Asymmetric allylic amination catalyzed b
โœ Tamio Hayashi; Kohei Kishi; Akihiro Yamamoto; Yoshihiko Ito ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 298 KB

A palladium complex bearing chiml (hydroxyalkyl)ferrocenylphosphine ligand was found to be a highly regio-and stereoselective catalyst for the asymmetric allylic amination of 2butenyl acetates with benzylamine, the nucleophilic attack of the amine taking place selectively on the more substituted end