## Abstract Isoquinolines (II) and (IV) are prepared under optimized conditions with a view to high enantioselectivities and elimination of side product formation.
Asymmetric Synthesis of (−)-Aurantioclavine via Palladium-Catalyzed Intramolecular Allylic Amination
✍ Scribed by Suetsugu, Satoshi; Nishiguchi, Hiromi; Tsukano, Chihiro; Takemoto, Yoshiji
- Book ID
- 121473184
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 437 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
Synthesis of potential antiparisitic 5'-aminonucloesides such as 10 could not be accomplished using standard amination procedures. Palladium(0)-catalyzed amination of cyclic allylic acetates with benzylamine or phthalimide gave the corresponding protected amines. This method was then extended to the
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