Palladium(0)-catalyzed azidation of allyl esters with trimethylsilyl azide
β Scribed by M. Safi; R. Fahrang; D. Sinou
- Book ID
- 103404795
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 204 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Palladium catalyzed reaction of ally1 acetates with azide ion gives ally1 azides, which are readily converted into the corresponding primary allylamines upon treatment with PPhS/NaOH. The catalytic transformation of allylic substrates via n-ally1 palladium complexes is now well d0cumented.l
A variety of 2-allylated-5-substituted tetrazoles were prepared in excellent yields through the reaction of alkyland arylidenemalononitriles, allyl acetates and trimethylsilyl azide in the presence of a palladium catalyst.
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