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Palladium chloride catalyzed cyclodimerization of 1-methylcyclopropene

โœ Scribed by Baird, R. L.; Weigert, Frank J.; Shapley, J. R.

Book ID
127212083
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
728 KB
Volume
92
Category
Article
ISSN
0002-7863

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## The palladium-catalyzed coupling reaction of aryl chlorides with various amines has been studied for the first time. Crucial for the success of this C-N bond forming reaction is the use of potassium tertbutoxide as base. Turn over numbers up to 900 and yields up to 80 % have been obtained.