Decarbonylation of tricyclic bridgehead acid chlorides 1 and 4 with palladium catalyst in the presence of tri-n-butylamine proceeded at 13O-OC to give exclusively stable disubstituted olefins 3 and 6, with probable intermediacy of the bridgehead olefins 2 and 5, respectively.
โฆ LIBER โฆ
Palladium catalyzed decarbonylation of aromatic acyl chlorides
โ Scribed by John W. Verbicky Jr.; Brent A. Dellacoletta; Louella Williams
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 112 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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