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Palladium-catalyzed carbonylation of N-heteroaromatic chloride

โœ Scribed by Ryo Takeuchi; Katsunobu Suzuki; Nobuhiro Sato

Publisher
Elsevier Science
Year
1991
Weight
789 KB
Volume
66
Category
Article
ISSN
0304-5102

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Palladium(II) catalyzed carbonylation of
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โœ Othman Hamed; Arab El-Qisairi; Patrick M. Henry ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 155 KB

Cyclic ketones react with PdCl 2 in methanol under a CO atmosphere to give mainly diesters by a ring cleavage reaction along with some chloro-substituted monoester. 13 CO labeling experiments indicate the major product is formed by a mechanism involving Pd(II)-CO 2 CH 3 insertion across the double b