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Synthesis of unsaturated alkoxy esters by palladium chloride-catalyzed oxidative carbonylation of conjugated dienes

โœ Scribed by Stuart B. Fergusson; Howard Alper


Publisher
Elsevier Science
Year
1986
Weight
241 KB
Volume
34
Category
Article
ISSN
0304-5102

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PdCl,( PPh,),, in combination with HCI, is highly active in the alkoxycarbonylation of cr$-ketocyclooletins to 3-oxocycloalkanecarboxylic acid esters. The reaction is region specific. The catalytic system is stabilized by addition of PPh,, which depresses the activity but prevents decomposition to i