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Palladium-Catalyzed Heck Reaction on 1-Alkoxy-1,3-dienes: A Regioselective γ-Arylation of α,β-Unsaturated Carbonyl Compounds.

✍ Scribed by Annamaria Deagostino; Cristina Prandi; Paolo Venturello

Publisher
John Wiley and Sons
Year
2004
Weight
186 KB
Volume
35
Category
Article
ISSN
0931-7597

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A Modular Approach to α-Arylated Carbony
A Modular Approach to α-Arylated Carbonyl Compounds via Indium Tris(bistriflylamide)-Catalyzed Regioselective Addition of β-Ketoesters to 1,3-Diynes
✍ Masaharu Nakamura; Kohei Endo; Eiichi Nakamura 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 116 KB 👁 1 views

## Abstract A modular synthesis of α‐arylated carbonyl compounds has been achieved by the combination of an indium‐catalyzed regioselective addition of β‐keto esters to conjugated diynes and a palladium‐catalyzed benzannulation reaction. Indium tris(bistriflylamide), In(NTf~2~)~3~, was found to be