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Palladium-catalyzed vinylation of alkyl vinyl ethers with enol triflates. A convenient synthesis of 2-alkoxy 1,3-dienes

โœ Scribed by Andersson, Carl Magnus; Hallberg, Anders


Book ID
118265748
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
576 KB
Volume
54
Category
Article
ISSN
0022-3263

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Palladium / Hydrovinylation / Cyclizations / Furan-2(5H)-ones The reaction of alkynes with vinyl triflates in the presence of in good to high yields. The reaction has been employed to develop a regioselective synthesis of 3-vinylfuran-2(5H)-ones catalytic amounts of Pd(OAc) 2 and HCOOK, omitting ph