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Palladium-catalyzed coupling of vinyl triflates with organostannanes. A short synthesis of pleraplysillin-1

โœ Scribed by Scott, William J.; Crisp, G. T.; Stille, J. K.

Book ID
120397851
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
367 KB
Volume
106
Category
Article
ISSN
0002-7863

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Palladium-catalyzed coupling of aryl tri
Palladium-catalyzed coupling of aryl triflates with organostannanes
โœ Echavarren, Antonio M.; Stille, J. K. ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 984 KB

The palladium-catalyzed coupling reaction of aryl triflates with alkyl, vinyl, acetylenic, and aryl tin reagents in the presence of lithium chloride takes place in high yields under mild conditions. However, allyltrialkyltin reagents coupled in lower yields, and unselective transfer of the allyl gro