Palladium-catalysed vinylation of allylic alcohols with enol triflates. A convenient synthesis of conjugated dienols
โ Scribed by Emilia Bernocchi; Sandro Cacchi; Pier Giuseppe Ciattini; Enrico Morera; Giorgio Ortar
- Book ID
- 108381479
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- French
- Weight
- 292 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Heck vinylation of tertiav allylic alcohols with iodo-acetal Ic, followed by an acid catalysed acetal hydrolysis-dehydration reaction, furnished isoprenoid aldehydes regioselectively in high yields.
A new access to ally1 silanes by the Ni and Pd catalysed cross-coupling reactions of vinyl selenides and t&nethylsilylmethylmagnesium chloride @ME / Rfx / 65-83 9% yield) is reported. As a result of the progressive recognition of their unique chemical reactivity, organosilicon compounds find increa