Nickel and palladium catalysed coupling of vinyl selenides with trimethylsilylmethylmagnesium chloride : A new synthesis of allyl silanes

✍ Scribed by Làszlò Hevesi; Bernard Hermans; Christophe Allard

• Publisher: Elsevier Science
• Year: 1994
• Tongue: French
• Weight: 172 KB
• Volume: 35
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)73479-4

✦ Synopsis

A new access to ally1 silanes by the Ni and Pd catalysed cross-coupling reactions of vinyl selenides and t&nethylsilylmethylmagnesium chloride @ME / Rfx / 65-83 9% yield) is reported.

As a result of the progressive recognition of their unique chemical reactivity, organosilicon compounds find increasing applications in organic synthesis 1. Among others, ally1 silanes are of particular importance 2, and a fair variety of methods are now available for their preparation 3. On the other hand, it has also been recognised that transition metal (especially nickel and palladium) catalysed C-C bond forming reactions