Palladium-catalyzed thiono-thiolo allylic rearrangement of O-allyl phosphoro- and phosphonothionates

Palladium catalyzed thiono-thiolo allyli

Palladium catalyzed thiono-thiolo allylic rearrangement of o-allyl phosphoro- and phosphonothionates

✍ Yoshimi Yamada; Kunio Mukai; Hirosuke Yoshioka; Yoshinao Tamaru; Zen-ichi Yoshid 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 220 KB

A new thiono-thiolo allylic rearrangement of phosphoro-and phosphonothionates with Pd(PPh3)4 catalyst is described, where a variety of thionates are converted to the corresponding thiolates in excellent yields.

Palladium(O)-catalyzed allylic alkylatio

Palladium(O)-catalyzed allylic alkylation and amination of allylic phosphates

✍ Yoshio Tanigawa; Kazuaki Nishimura; Akihiko Kawasaki; Shun-Ichi Murahashi 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 237 KB

Ally1 diethyl phosphates (\_1) can be easily substituted with malonates and amines in the presence of palladium(O) catalyst. Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate Cl,b) with high r

ChemInform Abstract: Palladium(0) Cataly

ChemInform Abstract: Palladium(0) Catalyzed Enantioselective Rearrangement of O-Allylic Thiocarbamates to S-Allylic Thiocarbamates: Asymmetric Synthesis of Allylic Thiols.

✍ Achim Boehme; Hans-Joachim Gais 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Palladium(0)-Cataly

ChemInform Abstract: Palladium(0)-Catalyzed Enantioselective O,S-Rearrangement of Racemic O-Allylic Thiocarbamates: A New Entry to Enantioenriched Allylic Sulfur Compounds.

✍ Hans-Joachim Gais; Achim Boehme 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Palladium-Catalyzed Enantioselective 1,3

Palladium-Catalyzed Enantioselective 1,3-Rearrangement of Racemic Allylic Sulfinates: Asymmetric Synthesis of Allylic Sulfones and Kinetic Resolution of an Allylic Sulfinate.

✍ Thomas Jagusch; Hans-Joachim Gais; Oleg Bondarev 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 136 KB 👁 2 views

Palladium-Catalyzed Enantioselective 1,3

Palladium-Catalyzed Enantioselective 1,3-Rearrangement of Racemic Allylic Sulfinates: Asymmetric Synthesis of Allylic Sulfones and Kinetic Resolution of an Allylic Sulfinate

✍ Jagusch, Thomas; Gais, Hans-Joachim; Bondarev, Oleg 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 106 KB