Palladium catalyzed thiono-thiolo allylic rearrangement of o-allyl phosphoro- and phosphonothionates
β Scribed by Yoshimi Yamada; Kunio Mukai; Hirosuke Yoshioka; Yoshinao Tamaru; Zen-ichi Yoshida
- Book ID
- 104238111
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 220 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
A new thiono-thiolo allylic rearrangement of phosphoro-and phosphonothionates with Pd(PPh3)4 catalyst is described, where a variety of thionates are converted to the corresponding thiolates in excellent yields.
π SIMILAR VOLUMES
Ally1 diethyl phosphates (\_1) can be easily substituted with malonates and amines in the presence of palladium(O) catalyst. Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate Cl,b) with high r
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v