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Palladium-Catalyzed Mono-α-Arylation of Acetone with Aryl Imidazolylsulfonates

✍ Scribed by Prof. Dr. Lutz Ackermann; Dr. Vaibhav P. Mehta

Book ID
112020379
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
396 KB
Volume
18
Category
Article
ISSN
0947-6539

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Aliphatic linear and a-branched aldehydes efficiently undergo arylation at the a-position upon treatment with aryl bromides using an appropriate palladium catalyst system that is capable of overcoming aldol condensation of the substrates.