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Palladium catalyzed direct α-arylation of α,α-difluoroketones with aryl bromides

✍ Scribed by Chen Guo; Ruo-Wen Wang; Feng-Ling Qing


Book ID
119297086
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
673 KB
Volume
143
Category
Article
ISSN
0022-1139

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Palladium-catalyzed α-arylation of aldeh
✍ Yoshito Terao; Yuichi Fukuoka; Tetsuya Satoh; Masahiro Miura; Masakatsu Nomura 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 89 KB

Aliphatic linear and a-branched aldehydes efficiently undergo arylation at the a-position upon treatment with aryl bromides using an appropriate palladium catalyst system that is capable of overcoming aldol condensation of the substrates.