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Palladium-Catalyzed Direct α-Arylation of Methyl Sulfones with Aryl Bromides

✍ Scribed by Zheng, Bing; Jia, Tiezheng; Walsh, Patrick J.

Book ID
120173756
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
355 KB
Volume
15
Category
Article
ISSN
1523-7060

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✍ Yoshito Terao; Yuichi Fukuoka; Tetsuya Satoh; Masahiro Miura; Masakatsu Nomura 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 89 KB

Aliphatic linear and a-branched aldehydes efficiently undergo arylation at the a-position upon treatment with aryl bromides using an appropriate palladium catalyst system that is capable of overcoming aldol condensation of the substrates.