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Palladium-Catalyzed Heteroannulation of 1,3-Dienes To Form α-Alkylidene-γ-butyrolactones

✍ Scribed by Gagnier, Steve V.; Larock, Richard C.

Book ID
127144811
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
215 KB
Volume
65
Category
Article
ISSN
0022-3263

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13, y-disubstituted (x-alkylidene-y-butyrolactones with cis or trans relative configurations were synthesized in both optically active forms from readily available homochiral allylic 2-alkynoates by Pd(II) catalysis in the presence of CuX2 and LiX Synthesis of homochiral compounds as candidates for