𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Palladium-Catalyzed Enantioselective Diboration of Prochiral Allenes

✍ Scribed by Pelz, Nicholas F.; Woodward, Angela R.; Burks, Heather E.; Sieber, Joshua D.; Morken, James P.

Book ID
127021842
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
41 KB
Volume
126
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Platinum(0)-catalyzed diboration of alle
Platinum(0)-catalyzed diboration of allenes with bis(pinacolato)diboron
✍ Tatsuo Ishiyama; Takahiro Kitano; Norio Miyaura πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 248 KB

Addition of bis(pinacolato)diboroon [(Me,C,O,)B-B(O,C#e,)] to various allenes was carried out in excellent yields in the presence of Pt(PPh,), at 80 T or Pt(dba)J(c-Hex)g at 50 "c. The addition to internal double bond was predominant for monosubstituted allenes, whereas the terminal diboration produ

Palladium-catalyzed synthesis of allenes
Palladium-catalyzed synthesis of allenes.
✍ TuyΓͺt Jeffery-Luong; GΓ©rard Linstrumelle πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 96 KB

Substituted allenes are selectively obtained in good yields from the reaction of Grignard reagents with propargylic or allenic halides in the presence of catalytic amounts of palladium chloride, triphenylphosphine and diisobutyl aluminum hydride, in