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Palladium-Catalyzed Direct Alkenylation of 2-Oxazolones: An Entry to 3,4,5-Trisubstituted 2-Oxazolones

✍ Scribed by Lu, Zenghui; Luo, Fang; Wang, Lina; Zhu, Gangguo

Book ID
121307007
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
492 KB
Volume
78
Category
Article
ISSN
0022-3263

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The chemistry of 2-alkenyl-5(4H)-oxazolo
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## Abstract A new family of aspartic acid derivatives is obtained through cycloaddition reactions of oxazolones (I) with allenoate (II), providing restricted cyclopentanyl aspartic acid analogues (III) and (IV) under mild conditions.