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ChemInform Abstract: Phosphine-Catalyzed [3 + 2] Cycloadditions of 2-Phenyl-4-arylidene-5(4H)-oxazolones with Allenoate: A Concise Synthesis of Aspartic Acid Analogues.

✍ Scribed by You-Quan Zou; Chao Li; Jian Rong; Hao Yan; Jia-Rong Chen; Wen-Jing Xiao

Publisher
John Wiley and Sons
Year
2011
Weight
33 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A new family of aspartic acid derivatives is obtained through cycloaddition reactions of oxazolones (I) with allenoate (II), providing restricted cyclopentanyl aspartic acid analogues (III) and (IV) under mild conditions.

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