Palladium-catalyzed cross-coupling of aryldiazonium tetrafluoroborate salts with arylboronic esters
β Scribed by Douglas M Willis; Robert M Strongin
- Book ID
- 104210685
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 97 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The first synthesis of arylboronic esters via the coupling of bis(pinacolato)diboron with easily prepared aryldiazonium tetrafluoroborate salts is reported. The palladium-catalyzed borylation reaction proceeds efficiently under mild reaction conditions in the absence of a base to afford various func
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## Abstract A propertyβactivity relationship study of various palladium supported on charcoal (Pd/C) catalysts has been undertaken for the Heck reaction of aryldiazonium tetrafluoroborate with acrylates. The optimized protocol enables the crossβcoupling with a low loading of palladium at room tempe