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Palladium-Catalyzed CC Bond Formation To Construct 1,4-Diketones under Mild Conditions

โœ Scribed by Chao Liu; Yi Deng; Jing Wang; Yingying Yang; Shan Tang; Prof. Aiwen Lei


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
361 KB
Volume
123
Category
Article
ISSN
0044-8249

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โœฆ Synopsis


Scheme 1. Approaches to 1,4-diketone synthesis between two carbonylsubstituted methyl units.


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Efficient Palladium-Catalyzed Oxidative
โœ Hanjie Mo; Weiliang Bao ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 169 KB ๐Ÿ‘ 2 views

## Abstract An efficient oxidative crossโ€coupling reaction between 1,3โ€diarylpropenes and indoles in the presence of palladium chloride was achieved with 2,3โ€dichloroโ€5,6โ€dicyanoquinone (DDQ) as oxidant. The reaction afforded 1,3โ€diphenylallylindoles in moderate to high yields under mild conditions