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ChemInform Abstract: Iron-Promoted C—C Bond Cleavage of 1,3-Diketones: A Route to 1,2-Diketones under Mild Reaction Conditions.

✍ Scribed by Lehao Huang; Kai Cheng; Bengben Yao; Yongju Xie; Yuhong Zhang


Publisher
John Wiley and Sons
Year
2011
Weight
35 KB
Volume
42
Category
Article
ISSN
0931-7597

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BMPD, a Novel C 2 -Chiral 1,3-Diketone Ligand; Synthesis and Application to an Asymmetric Catalytic Reaction. -A BMPDyttrium complex is found to be an efficient catalyst for the asymmetric silylcyanation of aldehydes. Aromatic aldehydes, except those with electronwithdrawing groups, show good to ex