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Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of Arylboronic Acids with Aryl Electrophiles: Synthesis of Biaryl Ketones

โœ Scribed by Ishiyama, Tatsuo; Kizaki, Hiroe; Hayashi, Takahiro; Suzuki, Akira; Miyaura, Norio

Book ID
120777117
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
86 KB
Volume
63
Category
Article
ISSN
0022-3263

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The cross-coupling reaction of arylboronic acids (1.3 equivs) with aryl methanesulfonates was carded out in the presence of anickel(O) catalyst(3 tool%) and K3PO~,nH20 (3 equivs). The use of toluene as the solvent and the nickel(O)-dppf catalyst prepared from NiC~(dppf) plus dppf with BuLi were reco