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Palladium-Catalyzed Cross-Coupling Reaction of Heteroaryltriolborates with Aryl Halides for Synthesis of Biaryls

โœ Scribed by Miyaura, Norio; Yamamoto, Yasunori; Takizawa, Miho; Yu, Xiao-Qiang

Book ID
119953493
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2010
Tongue
English
Weight
716 KB
Volume
80
Category
Article
ISSN
0385-5414

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Synthesis of unsymmetrical biaryls via p
Synthesis of unsymmetrical biaryls via palladium-catalyzed coupling reaction of aryl halides
โœ Jwanro Hassan; Chokri Hathroubi; Christel Gozzi; Marc Lemaire ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 71 KB

Unsymmetrical biaryls bearing electron-donating and electron-withdrawing functional groups have been obtained in an efficient manner by Pd-catalyzed coupling of aryl halides. Aryl bromides react with aryl iodides to yield unsymmetrical biaryls with marked selectivity.