✦ LIBER ✦

Palladium-catalyzed asymmetric hydroesterification of α-methylstyrene by the use of chiral dibenzophospholes as ligands

✍ Scribed by Teruyuki Hayashi; Masato Tanaka; Ikuei Ogata

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 146 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95099-3

No coin nor oath required. For personal study only.

✦ Synopsis

Asymmetric carbonylation is a useful reaction for the syntheses of optically active carbonyl compounds some of which could be intermediates for medicines and perfumes. We have reported') that a diphosphine (Da) , analogous to (-)-Diop, which has the SH-dibenzophospholyl group (DBP) in place of the diphenylphosphino -

📜 SIMILAR VOLUMES

The asymmetric hydrocarboalkoxylation of

The asymmetric hydrocarboalkoxylation of olefins catalyzed by palladium-chiral bis(dibenzophosphole) complexes

✍ Teruyuki Hayashi; Masato Tanaka; Ikuei Ogata 📂 Article 📅 1984 🏛 Elsevier Science ⚖ 942 KB

ChemInform Abstract: Asymmetric Inductio

ChemInform Abstract: Asymmetric Induction Reactions. Part 7. Palladium-Catalyzed Asymmetric α-Allylations of Carbonyl Compounds Using Chiral Sulfonamides as Chiral Ligands.

✍ K. HIROI; A. HIDAKA; R. SEZAKI; Y. IMAMURA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

Bulky Chiral Carbene Ligands and Their A

Bulky Chiral Carbene Ligands and Their Application in the Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides

✍ E. Peter Kündig; Thomas M. Seidel; Yi-xia Jia; Gérald Bernardinelli 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 1 views

Bulky Chiral Carbene Ligands and Their A

Bulky Chiral Carbene Ligands and Their Application in the Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides

✍ E. Peter Kündig; Thomas M. Seidel; Yi-xia Jia; Gérald Bernardinelli 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 2 views

Synthesis of Novel Planar Chiral Ferroce

Synthesis of Novel Planar Chiral Ferrocene and Cyclopentadienyl Manganese Tricarbonyl Derivatives and Their Use as Chiral Ligands in the Palladium-Catalyzed Asymmetric Allylic Alkylation.

✍ Jae Hoon Lee; Seung Uk Son; Young Keun Chung 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 98 KB 👁 2 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Synthesis of novel planar chiral ferroce

Synthesis of novel planar chiral ferrocene and cyclopentadienyl manganese tricarbonyl derivatives and their use as chiral ligands in the palladium-catalyzed asymmetric allylic alkylation

✍ Jae Hoon Lee; Seung Uk Son; Young Keun Chung 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 243 KB

We have shown that cymantrene derivatives are better P,N-chelate ligands for palladium-catalyzed allylic alkylation than ferrocenes, which have a similar pentagonal ligand structure to cymantrene derivatives. In particular, the PPh 3 -substituted cymantrene gave a higher enantioselectivity (>98%).