Asymmetric carbonylation is a useful reaction for the syntheses of optically active carbonyl compounds some of which could be intermediates for medicines and perfumes. We have reported') that a diphosphine (Da) , analogous to (-)-Diop, which has the SH-dibenzophospholyl group (DBP) in place of the d
The asymmetric hydrocarboalkoxylation of olefins catalyzed by palladium-chiral bis(dibenzophosphole) complexes
β Scribed by Teruyuki Hayashi; Masato Tanaka; Ikuei Ogata
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 942 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0304-5102
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swmnary : Optically active norbornyl and l-phenylethyl alcohols and bromides were obtained, res- pectively, from norbornyl-and l-phenylethylpentafluorosilicates which were prepared by asymmetric hydrosilylation of norbornene and styrene with trichlorosilane catalyzed by a chiral ferrocenylphosphine-
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