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Palladium-catalyzed amination in the synthesis of polyazamacrocycles

✍ Scribed by I. P. Beletskaya; A. D. Averin; A. G. Bessmertnykh; F. Denat; R. Guilard

Book ID
111465420
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
433 KB
Volume
46
Category
Article
ISSN
1070-4280

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## Abstract Pd‐Catalyzed amination of 3,5‐dibromo‐ and 3,5‐dichloropyridine (**1a** and **1b**, resp.) with linear polyamines **2** leads to the formation of a new family of pyridine‐containing macrocycles **3** with an ‘__exo__’‐oriented pyridine N‐atom (__Schemes 1__ and __2__). The dependence of