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Palladium-catalyzed amination of dihalobenzenes

โœ Scribed by I. P. Beletskaya; A. G. Bessmertnykh; R. A. Mishechkin; R. Guilard

Book ID
105596008
Publisher
Springer
Year
1998
Tongue
English
Weight
160 KB
Volume
47
Category
Article
ISSN
1573-9171

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Palladium-catalyzed amination of aryl ch
Palladium-catalyzed amination of aryl chlorides
โœ Nagavelli Prabhakar Reddy; Masato Tanaka ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

Pd(PCy3)CI 2 (Cy = cyclohexyi) catalyzed the rcactioa of aryl cldmides and ~,,octdary amln~ in the pre~ncยข of NaOtBu to give the ~g aryl amines in good to excellent yields. In of dte reactions, an excess amouat of aryl chloride (atyl chloride/amine = 2) improved the yields.