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Arylation of adamantanamines: II. Palladium-catalyzed amination of dihalobenzenes with adamantylalkanamines

✍ Scribed by A. D. Averin; M. A. Ulanovskaya; A. K. Buryak; E. N. Savel’ev; B. S. Orlinson; I. A. Novakov; I. P. Beletskaya


Book ID
111465568
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
395 KB
Volume
46
Category
Article
ISSN
1070-4280

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Palladium-catalyzed amination of aryl ch
✍ Nagavelli Prabhakar Reddy; Masato Tanaka 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 206 KB

Pd(PCy3)CI 2 (Cy = cyclohexyi) catalyzed the rcactioa of aryl cldmides and ~,,octdary amln~ in the pre~nc¢ of NaOtBu to give the ~g aryl amines in good to excellent yields. In of dte reactions, an excess amouat of aryl chloride (atyl chloride/amine = 2) improved the yields.