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Application of Palladium-Catalyzed Amination to the Synthesis of Polyazamacrocycles Containing 3,5-Disubstituted Pyridine.

✍ Scribed by Irina P. Beletskaya; Alexei D. Averin; Olesya A. Ulanovskaya; Ilya A. Fedotenko; Anatolii A. Borisenko; Marina V. Serebryakova; Franck Denat; Roger Guilard


Publisher
John Wiley and Sons
Year
2006
Weight
19 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Palladium-Catalyzed Amination of 3,5-Dih
✍ Alexei D. Averin; Olesya A. Ulanovskaya; Ilya A. Fedotenko; Anatolii A. Borisenk 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 302 KB 👁 1 views

## Abstract Pd‐Catalyzed amination of 3,5‐dibromo‐ and 3,5‐dichloropyridine (**1a** and **1b**, resp.) with linear polyamines **2** leads to the formation of a new family of pyridine‐containing macrocycles **3** with an ‘__exo__’‐oriented pyridine N‐atom (__Schemes 1__ and __2__). The dependence of