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Palladium-Catalyzed Allylic Alkylation of Optically Active α-Alkenyl-α-acyloxytrialkylsilane.

✍ Scribed by Kazuhiko Sakaguchi; Takeshi Yamada; Yasufumi Ohfune

Publisher
John Wiley and Sons
Year
2005
Weight
28 KB
Volume
36
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of α-Aryl Ketones
✍ Barry M. Trost; Gretchen M. Schroeder; Jesper Kristensen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 1 views

The generation of quatenary chiral centers through catalytic asymmetric alkylation of ketone enolates has been the subject of investigation in recent years. [1] The palladiumcatalyzed asymmetric allylic alkylation (AAA) of prochiral nucleophiles represents one such strategy for the creation of quate