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Palladium-Catalyzed Allylic Alkylation of α-Sulfinyl Carbanions under Biphasic Conditions.

✍ Scribed by Guillaume Maitro; Guillaume Prestat; David Madec; Giovanni Poli

Publisher
John Wiley and Sons
Year
2006
Weight
32 KB
Volume
37
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of α-Aryl Ketones
✍ Barry M. Trost; Gretchen M. Schroeder; Jesper Kristensen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 1 views

The generation of quatenary chiral centers through catalytic asymmetric alkylation of ketone enolates has been the subject of investigation in recent years. [1] The palladiumcatalyzed asymmetric allylic alkylation (AAA) of prochiral nucleophiles represents one such strategy for the creation of quate