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Palladium-Catalyzed Arylation of α,α-Difluoro-allylic-β-hydroxyester.

✍ Scribed by Xiang Fang; Xueyan Yang; Xianjin Yang; Min Zhao; Guorong Chen; Fanhong Wu


Publisher
John Wiley and Sons
Year
2007
Weight
25 KB
Volume
38
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Asymmetric Allylic A
✍ Barry M. Trost; Gretchen M. Schroeder; Jesper Kristensen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 1 views

The generation of quatenary chiral centers through catalytic asymmetric alkylation of ketone enolates has been the subject of investigation in recent years. [1] The palladiumcatalyzed asymmetric allylic alkylation (AAA) of prochiral nucleophiles represents one such strategy for the creation of quate