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Palladium-Catalyzed Addition of Pronucleophiles to Allenes

โœ Scribed by Trost, Barry M.; Gerusz, Vincent J.


Book ID
120661736
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
862 KB
Volume
117
Category
Article
ISSN
0002-7863

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Palladium catalyzed addition of carbon p
โœ Vladimir Gevorgyan; Chie Kadowaki; Matthew M. Salter; Isao Kadota; Shinichi Sait ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 461 KB

Palladium catalyzed addition of certain carbon pronucleophiles 2 to conjugated enynes l afforded the corresponding allenes 3 in good to excellent yields. The most reactive methynes such o.~ methylmalononitrile 2e enabled to undezgo double addition leading to alkenes 4. Catalyst optimization supporte