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Palladium-Catalyzed Addition of Nitrogen Pronucleophiles to Alkylidenecyclopropanes

✍ Scribed by Siriwardana, Amal I.; Kamada, Michiru; Nakamura, Itaru; Yamamoto, Yoshinori

Book ID
120274331
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
145 KB
Volume
70
Category
Article
ISSN
0022-3263

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Alkylidenecyclopropanes react with ketones under neutral conditions, in the presence of a catalytic amount of Pd(PPh 3 ) 4 to afford the corresponding a-allylated ketone products, in moderate to good yields.