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Palladium catalysed allylic substitution via in situ activation of allylic alcohols

✍ Scribed by R. Kumareswaran; Yashwant D. Vankar

Book ID
108385348
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
204 KB
Volume
38
Category
Article
ISSN
0040-4039

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The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl) cyclopentane/[PdCl(C 3 H 5 )] 2 system catalyses allylic amination in water with very high substrate/catalyst ratio in good yields. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presen