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Palladium-tetraphosphine catalysed allylic substitution in water

✍ Scribed by Marie Feuerstein; Dorothée Laurenti; Henri Doucet; Maurice Santelli

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
68 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)

cyclopentane/[PdCl(C 3 H 5 )] 2 system catalyses allylic amination in water with very high substrate/catalyst ratio in good yields. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.

📜 SIMILAR VOLUMES

Enantioselective palladium catalysed all
Enantioselective palladium catalysed allylic substitution with thienyl oxazoline ligands
✍ Christopher G Frost; Jonathan MJ Williams 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 271 KB

The use of homochiral oxaxolines as ligands in metal catalysed reactions has recently been mceiving a gmat deal of attention. For example, enantioselective cyclopropanation,l hydrosilylation2 and Diels AldeS reactions have been reported to proceed with remarkably high levels of enantioselectivity.