Palladium catalysed allylic acetoxylation of dialkyl allyl phosphonates.
✍ Scribed by Bruno Principato; Michel Maffei; Chhan Siv; Gérard Buono; Gilbert Peiffer
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 604 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
The heteropolyacid H, [PMo,,V,O,,] is an effective oxygen-activating catalyst in palladium-catalyzed aerobic allylic acetoxylation of cyclohexene.
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl) cyclopentane/[PdCl(C 3 H 5 )] 2 system catalyses allylic amination in water with very high substrate/catalyst ratio in good yields. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presen
Allyl acetates were synthesised from allenes utilising methodology based on the general reactivity of p-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc) 2 /PPh 3 as the c